Chemists design novel method for generating sustainable fuel: Study

Ohio, July 21: For many years, chemists have been striving to create high-value products from waste molecules. Now, an international team of experts is looking into methods to use electricity to speed up the process.

In their study, recently published in Nature Catalysis, researchers demonstrated that carbon dioxide, a greenhouse gas, can be converted into a type of liquid fuel called methanol in a highly efficient manner.

This procedure involved taking cobalt phthalocyanine (CoPc) molecules and uniformly spreading them over carbon nanotubes, which are graphene-like tubes with unique electrical characteristics. An electrolyte solution was present on their surface, and when an electrical current was sent across it, CoPc molecules could accept electrons and use them to convert carbon dioxide into methanol.

Using a special method based on in-situ spectroscopy to visualize the chemical reaction, researchers for the first time saw those molecules convert themselves into either methanol or carbon monoxide, which is not the desired product. They found that which path the reaction takes is decided by the environment where the carbon dioxide molecule reacts.

Tuning this environment by controlling how the CoPc catalyst was distributed on the carbon nanotube surface allowed carbon dioxide to be as much as eight times more likely to produce methanol, a discovery that could increase the efficiency of other catalytic processes and have a widespread impact on other fields, said Robert Baker, co-author of the study and a professor in chemistry and biochemistry at The Ohio State University.

"When you take carbon dioxide and convert it to another product, there are many different molecules you can make," he said. "Methanol is definitely one of the most desirable because it has such a high energy density and can be used directly as an alternative fuel."

While transforming waste molecules into useful products isn't a new phenomenon, until now, researchers have often been unable to watch how the reaction actually takes place, a crucial insight into being able to optimize and improve the process.

"We might empirically optimize how something works, but we don't really have an understanding of what makes it work, or what makes one catalyst work better than another catalyst," said Baker, who specializes in surface chemistry, the study of how chemical reactions change when they occur on the face of different objects. "These are very difficult things to answer."

But with the help of special techniques and computer modeling, the team has come significantly closer to grasping the complex process. In this study, researchers used a new type of vibrational spectroscopy, which allowed them to see how molecules behave on the surface, said Quansong Zhu, the lead author of the study and former Ohio State Presidential Scholar whose challenging measurements were vital to the discovery.

"We could tell by their vibrational signatures that it was the same molecule sitting in two different reaction environments," said Zhu. "We were able to correlate that one of those reaction environments was responsible for producing methanol, which is valuable liquid fuel." According to the study, deeper analysis also found these molecules were directly interacting with supercharged particles called cations that enhanced the process of methanol formation.

More research is needed to learn more about what else these cations enable, but such a finding is key to achieving a more efficient way to create methanol, said Baker.

"We're seeing systems that are very important and learning things about them that have been wondered about for a long time," said Baker. "Understanding the unique chemistry that happens at a molecular level is really important to enabling these applications."

Besides being a low-cost fuel for vehicles like planes, cars and shipping boats, methanol produced from renewable electricity could also be utilized for heating and power generation, and to advance future chemical discoveries.

"There's a lot of exciting things that can come next based on what we've learned here, and some of that we're already starting to do together," said Baker. "The work is ongoing."

Co-authors include Conor L. Rooney and Hailiang Wang from Yale University, Hadar Shema and Elad Gross from Hebrew University, and Christina Zeng and Julien A. Panetier from Binghamton University.